Product ID:WELDING SUPPLIES-1, S00745 QA INSPECT DEVELOPER
MSDS Date:09/01/1996
FSC:6850
NIIN:00N088496
MSDS Number: CHPFM

SHERWIN-WILLIAMS CO

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-292-7400

Info Phone: 800-240-0248

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 8%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 22%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

132.

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 62%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM; 450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TALC

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 8%

OSHA PEL 20 MPPCF

ACGIH TLV: 2 MG/M3 RDUST

30% BY WEIGHT PER BAAQMD RULE

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

EXTREMELY FLAMMABLE. FLASH BELOW 21F.

RTECS: 9999999ZZ

IN INGREDS MAY CAUSE ADVERSE EFTS TO

RTECS: 9999999ZZ

ASSOC RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN &

RTECS: 9999999ZZ

DO NOT INCINERATE. DEPRESSURIZE CNTNR.

RTECS: 9999999ZZ

KEEP AREA VENTD - DO NOT

RTECS: 9999999ZZ

TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY

RTECS: 9999999ZZ

BONDING & GROUNDING PROCS. CONTENTS UNDER PRESS. DO

RTECS: 9999999ZZ

HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER &

RTECS: 9999999ZZ

NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF

RTECS: 9999999ZZ

OR FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG

RTECS: 9999999ZZ

HANDS AFTER USING. THESE COATINGS MAY CNTN MATLS

RTECS: 9999999ZZ

IN INGRED SECTION) WHICH MAY BE PRESENT AT HAZ

RTECS: 9999999ZZ

NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMITS FOR

RTECS: 9999999ZZ

(RESPIRABLE FRACTION), OSHA PEL 15 MG/M3 (TDUST), 5

RTECS: 9999999ZZ

FOR DUST WHICH MAY BE GENERATED FROM THIS

RTECS: 9999999ZZ

OSHA STANDARDS 1910.94, 1910.107, 1910.108.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CHLOROCARBON MATLS HAVE PRDCED
SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE
SIMILAR EFT IN HUMANS. ADRENOMIMETICS (EG EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUST AINING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROCARBONS . IRRIT OF EYES, SKIN &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: RESP SYS. MAY CAUSE NERVOUS SYS
DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH,
DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO
VAPS/SPRAY MISTS. REDNESS & IT CHING OR BURNING SENSATION MAY
INDICATEEYE OR EXCESSIVE SKIN EXPOS. CHRONIC: PRLNGD OVEREXP TO
SOLVS LISTED (ING 7)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
FLUSH EYE S W/LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES. GET
MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. GET
MED ATTN.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.9%
Upper Limits:12.8%
Extinguishing Media:CARBON MONOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG
NOZZS ARE PREF. WATER MAY BE USED TO (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL HCL &
PHOSGENE . CLSD CNTNRS MAY EXPLODE (DUE TO BUILDUP OF PRESS) WHEN
EXPOS TO EXTREME HEAT. ISOLATE FROM HEAT, (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAM. KEEP AWAY
FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE
EXPLOSIVELY. DURING USE & UNTIL ALL (ING 10)
Other Precautions:NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFS. HEAT &/OR UV RADIATION
MAY CAUSE FORMATION OF HCL &/OR PHOSGENE . INTENTIONAL MISUSE BY
DELIB CONC & INHAL CONTENTS CAN BE HARMFUL (ING 15)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST LISTED MATLS. WHEN
SANDING/ABRADING DRIED FILM, WEAR DU ST/MIST RESP APPRVD BY NIOSH
(ING 20)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO LISTED
MATLS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO (ING 21)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: COOL CLSD CNTNRS TO PVNT PRESS BUILDUP & POSS
AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: ELEC
EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT SURFS REQS SPEC PRECS.
DURI NG EMER CNDTNS OVERREXP TO DECOMP PRODSMAY CAUSE HLTH HAZ.
SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. (ING 6)

Boiling Pt:B.P. Text:<395F,<202C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.96
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION.

Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM THIS PROD MAY ALSO
BE DEFINED AS HAZ DUE TO THE PRESENCE OF
1,1,1-TRICHLOROETHANE.(ING 9)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.